ISSN (0970-2083)
Gennady Petrovich Paramonov* and Vladimir Nikolayevich Kovalevskyi
Saint-Petersburg Mining University, 21 line, 2, Saint-Petersburg, 199106 Russia
Received date: April 06, 2017; Accepted date: April 08, 2017
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This article discusses the influence of explosive charge diameter and type of explosive substance on generation of fine dust. Dependences of dust generation intensity for various size fractions and dust concentration upon blasting for operation conditions of open-pit mines of building materials. Calculation procedures of dust and gas pollutions upon blasting operations are reviewed and analyzed. Sample calculation of dust and gas pollution according to the proposed procedure is given with consideration of gas dynamic processes in blasthole charging pocket, blasting and drilling parameters, properties of explosive substances and rock massif, including results of commercial approbation in open-pit mines of building materials. Results of commercial experiment are given, the known calculation procedures of dust and gas emissions upon blasting and drilling operations in open-pit mines are analyzed.
Dust, Concentration, Explosive charge, Explosive charge diameter, Detonation velocity, Open-pit mine, Blast, explosion
In Huge amounts of dust and gas are emitted into environment upon multiple blasts. The amount of explosive charge for multiple blasts in openpit mines reaches 300 t to 1000 t, and the weight of blasted rocks amounts to 5 million t. According to particle size distribution of blasted rocks of various strength it is established that in terms of 1 kg of explosive substance upon multiple blasts the dust and gas cloud contains from 80 g to 320 g of 20 μm size fraction (Adushkin, 1996). It has been shown in Beresnevich and Mikhailov, 1990; that specific amount of dust per unit of rocks depends on rock strength and increases with increase in mining depth and varies in the range of 30 g/m3 to 160 g/m3.
Nowadays several procedures for calculations of dust and gas environmental pollutions upon multiple blasts in open-pit mines are known, such as the procedure for calculations of harmful emissions (effluents) for open-pit mining (on the basis of specific performances) developed in Skochinsky Mining institute (Procedures of calculation of harmful emissions (effluents) for equipment of open-pit mines (on the basis of specific performances, 1990), Unified Program of air pollution estimation, Ecolog, ver. 3 (Integral Company), Mining operations, ver. 1.1.0.4 (Integral Company), and others. The software packages Ecolog, ver. 3.00 and Mining operations, ver 1.1.0.4 (Integral Company) are based on the procedures in procedures of calculation of harmful emissions (effluents) for equipment of openpit mines (on the basis of specific performances, 1990), however, they do not take into account energy properties of explosive substances (ES) and their detonation velocities, drilling and blasting parameters (borehole diameters and their amount, explosive charge weight in borehole). A procedure is discussed in (Menzhulin and Paramonov, 1997) which calculates dust size fractions generated in near zone of blast with accounting for the use of various explosive charge designs, ES types and properties of blasted massif. This procedure is based on the theory of destruction including kinetics of accumulation of induced fracturing resulted from blasting loads on rock massif with consideration for gas dynamic processes in explosive charge pockets, detonation properties of fractured rocks. This procedure is implemented in Dust software developed by Saint Petersburg Mining Institute. it should be mentioned that this procedure accounts for dust generation only in near zone of blast and does not account for dust generation due to additional crushing upon rock displacement.
This work proposes calculation procedure of dust generation with consideration for peculiar features of the above listed procedures, as well as reveals dependences estimating dust and gas emissions upon blasting of various ES on the basis of known blast parameters of ammonites: the most popular explosives for drilling and blasting.
The amount of pollutants emitted upon blasting in open-pit mines was determined in the course of experiments performed at OAO Kamennogorsk department of open-pit mines and ZAO Gavrilovskoe department of open-pit mines, Leningrad oblast. The experiments were performed with granite and granite gneiss, their Protodyakonov strength coefficient varies in the range of 12-14.
In order to approbate the calculation procedure with regard to conditions of Kamennogorsk deposit model experiments were performed with rock samples (Larichev, et al., 2009). Convergence of results of laboratory tests, calculations, measurements of dust and gas emissions (Procedures of calculation of harmful emissions (effluents) for equipment of openpit mines (on the basis of specific performances, 1990; Menzhulin and Paramonov, 1997; Larichev, et al., 2009a; Larichev, et al., 2010; Shmeleva, et al., 2006), obtained upon pilot multiple blasts, makes it possible to apply them for estimation of new ES types, to forecast polluting emissions upon blasting using boreholes of various diameters in deposits and open-pit mines, as well as to apply the proposed procedure in counter-explosive criminalistics for identification of ES type and weight on the basis explosion products, weight and size fractions of dust.
Numerical calculations (Larichev, et al., 2009) of dust generation according to the procedure in (Menzhulin and Paramonov, 1997), developed in Saint Petersburg Mining institute, confirmed their convergence with experimental data on the basis of weight estimation by size fractions generated upon blasting of borehole charges.
Analysis of experimental and calculated data Tables 1-4 using the procedures (Procedures of calculation of harmful emissions (effluents) for equipment of open-pit mines (on the basis of specific performances, 1990; Menzhulin and Paramonov, 1997) in (Larichev, et al., 2009; Larichev, et al., 2009a; Larichev, et al., 2010) and measurements of harmful pollutions (Shmeleva, et al., 2006) by OAO Kamennogorsk department of open-pit mines demonstrates that the dust amount generated upon blasting and calculations differ by not more than 15%, which confirms possibility of the developed procedure to estimate dust and gas generation.
ES type | Protodyakonov strength coefficient |
ES density, kg/m3 |
D, m/s | dBore , 10−3 m |
Gas emission coefficient for ammonite |
Dust emission coefficient for ammonite |
---|---|---|---|---|---|---|
Ammonite No. 6 ZhV | 12-14 | 950 | 4500 | |||
252 | 1 | 1 | ||||
220 | 0.947 | 0.663 | ||||
165 | 0.614 | 0.606 | ||||
130 | 0.682 | 0.586 | ||||
112.5 | 0.666 | 0.423 | ||||
75 | 0.833 | 0.165 | ||||
1200 | 5300 | 252 | 1.384 | 1.403 | ||
220 | 1.313 | 1.065 | ||||
165 | 0.852 | 0.912 | ||||
130 | 0.945 | 0.831 | ||||
112.5 | 0.923 | 0.598 | ||||
75 | 1.155 | 0.233 | ||||
Grammonite 79/21 | 870 | 4300 | 252 | 0.698 | 0.907 | |
220 | 0.920 | 0.616 | ||||
165 | 0.596 | 0.549 | ||||
130 | 0.590 | 0.530 | ||||
112.5 | 0.647 | 0.388 | ||||
75 | 0.810 | 0.151 | ||||
1200 | 4800 | 252 | 1.342 | 1.156 | ||
220 | 1.276 | 0.770 | ||||
165 | 0.826 | 0.685 | ||||
130 | 0.921 | 0.642 | ||||
112.5 | 0.898 | 0.493 | ||||
75 | 1.123 | 0.194 | ||||
Sibirite | 1000 | 5080 | 252 | 0.346 | 0.355 | |
220 | 0.324 | 0.197 | ||||
165 | 0.213 | 0.185 | ||||
130 | 0.234 | 0.177 | ||||
112.5 | 0.229 | 0.130 | ||||
75 | 0.287 | 0.050 | ||||
1200 | 6000 | 252 | 0.473 | 0.445 | ||
220 | 0.450 | 0.290 | ||||
165 | 0.293 | 0.269 | ||||
130 | 0.324 | 0.256 | ||||
112.5 | 0.317 | 0.183 | ||||
75 | 0.396 | 0.058 |
Table 1. Universal coefficients of dust and gas emissions
ES type | ES density, kg/ m3 |
D, m/s | dBore , 103m | Calculated dust weight kg /1kg ES |
Calculated gas weight kg /1kg ES |
---|---|---|---|---|---|
Ammonite No. 6 ZhV | 950 | 4500 | 252 | 0.110 | 0.063 |
220 | 0.073 | 0.060 | |||
165 | 0.067 | 0.039 | |||
130 | 0.064 | 0.043 | |||
112.5 | 0.047 | 0.042 | |||
75 | 0.018 | 0.052 | |||
1200 | 5300 | 252 | 0.154 | 0.087 | |
220 | 0.117 | 0.083 | |||
165 | 0.100 | 0.054 | |||
130 | 0.091 | 0.060 | |||
112.5 | 0.066 | 0.058 | |||
75 | 0.026 | 0.072 | |||
Grammonite 79/21 | 870 | 4300 | 252 | 0.099 | 0.044 |
220 | 0.068 | 0.058 | |||
165 | 0.060 | 0.038 | |||
130 | 0.058 | 0.037 | |||
112.5 | 0.043 | 0.041 | |||
75 | 0.017 | 0.051 | |||
1200 | 4800 | 252 | 0.127 | 0.085 | |
220 | 0.085 | 0.080 | |||
165 | 0.075 | 0.052 | |||
130 | 0.071 | 0.058 | |||
112.5 | 0.054 | 0.056 | |||
75 | 0.021 | 0.071 | |||
Sibirite | 1000 | 5080 | 252 | 0.039 | 0.022 |
220 | 0.022 | 0.020 | |||
165 | 0.020 | 0.013 | |||
130 | 0.019 | 0.015 | |||
112.5 | 0.014 | 0.014 | |||
75 | 0.005 | 0.018 | |||
1200 | 6000 | 252 | 0.049 | 0.030 | |
220 | 0.032 | 0.028 | |||
165 | 0.030 | 0.018 | |||
130 | 0.028 | 0.020 | |||
112.5 | 0.020 | 0.019 | |||
75 | 0.006 | 0.025 |
Table 2. Dust and gas emissions after blasting of 1 kg ES
Explosive substance | Brisancy, mm | Fugacity, cm3 | Detonating velocity, m/s | Density, g/cm3 | Heat of explosion, kJ/kg | Trinitrotoluene equivalent |
---|---|---|---|---|---|---|
Tetranitropentaerytrite | 16 | 500 | 7520 | 1510 | 5800 | 1.37 |
Ammonite No. 6ZhV | 14 | 360 | 4500 | 950 | 4355 | 1.03 |
Grammonite 79/21 | 25 | 360 | 4300 | 870 | 4300 | 1.02 |
Sibirite 1200 | 17 | 400 | 6000 | 1200 | 4100 | 0.96 |
Trinitrotoluene | 16 | 285 | 6600 | 1660 | 4228 | 1 |
Plastic explosive (PE-4) | 21 | 280 | 7000 | 1440 | 5440 | 1.28 |
Hexogen | 24 | 470 | 8380 | 1800 | 5500 | 1.3 |
Table 3. Properties of some explosive substances
Protodyakonov strength coefficient | Specific dust emission (qD , kg/m3), according to Skochinsky Mining Institute | Adjustment rock strength coefficients | Specific dust emission (qD , kg/m3), according to Skochinsky Mining Institute | Adjustment rock strength coefficients |
---|---|---|---|---|
For emulsified ES | For water-free ES | |||
2-4 | 0.015 | 0.3-0.33 | 0.03 | 0.27-0.33 |
4-6 | 0.02 | 0.4-0.44 | 0.04 | 0.36-0.44 |
6-8 | 0.025 | 0.5-0.55 | 0.05 | 0.45-0.55 |
8-10 | 0.03-0.04 | 0.66-0.8 | 0.06-0.08 | 0.66-0.72 |
10-12 | 0.04-0.045 | 0.89-0.9 | 0.08-0.09 | 0.81-0.88 |
12-14 | 0.045-0.05 | 1 | 0.09-0.11 | 1 |
14-16 | 0.05-0.06 | 1.11-1.2 | 0.11-0.13 | 1.18-1.22 |
16-18 | 0.06-0.08 | 1.33-1.6 | 0.13-0.16 | 1.44-1.46 |
Table 4. Adjustment rock strength coefficients of dust emission as a function of rock strength for water free ES and emulsified ES
1. Example of calculations of harmful emissions resulted from ammonite No. 6 ZhV using the procedure (Procedures of calculation of harmful emissions (effluents) for equipment of open-pit mines (on the basis of specific performances, 1990), of Skochinsky Mining institute for conditions of OAO Kamennogorsk department of open-pit mines in terms of single blast of 30 t ES, dBore = 252 mm , 950 / 3 ρES = kg m . The Protodyakonov strength coefficient of granite is in the range of 1 2-14.
Weight of harmful gases (carbon oxide, nitrogen oxides), emitted with dust and gas cloud (DGC):
Weight of harmful gases remaining in blasted rock mass (RM) and gradually released into environment:
Calculation of total weight of harmful gases emitted upon blast (in terms of conventional CO ):
Weight of solid particles (dust) emitted with DGC:
Total weigh of harmful substances emitted upon single blast:
Total weigh of harmful substances emitted upon single blast:
All coefficients Table 1 were calculated using the procedure in Menzhulin and Paramonov, 1997, which enable forecasting of dust and gas weights upon the use of various explosive boreholes, various types of ES with various detonation velocities and density.
Therefore, it would be reasonable to introduce the notions of ammonite dust equivalent and ammonite gas equivalent similar to trinitrotoluene equivalent, that is, amount (weight) of dust and gas after blasting of ammonite No. 6ZhV (density 950 kg/m3, detonation rate 4500 m/s) as one of the most widely used ES in open-pit mines.
is the coefficient of gas emission in terms of ammonite No. 6ZhV (density 950 kg/m3, detonation velocity 4500 m/s); is the coefficient of dust emission in terms of ammonite No. 6ZhV (density 950 kg/m3, detonation velocity 4500 m/s).
Therefore, in order to determine the amounts of gas and dust emitted upon blast it is required to calculate the amounts of dust and gas using Eqs. 1.1- 1.6 for ES: ammonite No. 6ZhV (density 950 kg/m3, detonation velocity 4500 m/s), and then to multiply by or , respectively.
Dust and gas emissions upon ES blasting in terms of 1 kg ES are summarized in Table 2.
The data are given for dust dN ≤ 300 μm according to the proposed procedure.
Using the data in Table 3 it is possible to interrelate the ES trinitrotoluene equivalent with dust or gas equivalents.
When ammonite No. 6ZhV with the density of 950 g/cm3 is used as ES, the emissions of dust with size fraction of dÍ ≤ 300 μm are 0.11÷0.018 kg/1 kg ES. Taking into account that 1 kg of ammonite No. 6 ZhV in terms of energy=1.03 kg of trinitrotoluene, upon blasting of 1 kg of trinitrotoluene with the density of 1660 g/cm3 the emissions of dust with size fraction of dÍ ≤ 300 μm are 0.1068÷0.017 kg/1 kg ES, hence, the proposed procedure can be applied in blasting technique upon determination of ES weight and composition.
In order to calculate dust and gas emissions in rocks with strength differing from that of granite (Protodyakonov strength coefficient of 12-14) it is required to apply conversion rock strength coefficients of dust emission summarized in Table 4.
Therefore, it is possible to estimate the difference in dust emissions under identical conditions varying only by strength of blasted rocks. For instance, 141.68 t of dust are generated at OAO Kamennogorsk department of open-pit mines in one year, provided that Protodyakonov strength coefficient of granite rocks varies in the range from 12 to 14, and in the case of rock blasting with the strength of 8-10 the dust emissions are 93.5 t/year to 113.344 t/year.
Table 5 illustrates application of ammonite dust and gas equivalents, as well as summarizes emitted amounts of dust and gas upon multiple blasts of various ES and borehole diameters.
ES type |
ES density, kg/m3 |
D, m/s |
dBore , 10−3 m |
Calculated dust weight * 103 kg / year |
Calculated dust weight ** 103 kg / year |
Calculated dust weight *** 103 kg / year |
Experimental dust weight 103 kg / year |
Calculated gas weight 103 kg / year |
---|---|---|---|---|---|---|---|---|
Ammonite No. 6 ZhV | 950 | 4500 | 252 | 59.81 | 118.8 | 118.8 | 141.68 | 67.68 |
220 | 39.46 | 78.8 | 64.08 | |||||
165 | 36.25 | 72.0 | 41.58 | |||||
130 | 35.09 | 69.6 | 46.14 | |||||
112.5 | 25.30 | 50.2 | 45.05 | |||||
75 | 9.89 | 19.6 | 56.38 | |||||
1200 | 5300 | 252 | 83.95 | 166.6 | 93.84 | |||
220 | 63.74 | 126.5 | 88.85 | |||||
165 | 54.54 | 108.3 | 57.65 | |||||
130 | 49.73 | 98.7 | 63.98 | |||||
112.5 | 35.76 | 71.0 | 62.46 | |||||
75 | 13.96 | 27.7 | 78.18 | |||||
Grammonite 79/21 | 870 | 4300 | 252 | 54.24 | 107.8 | 107.8 | 129.70 | 65.52 |
220 | 36.86 | 73.2 | 62.28 | |||||
165 | 32.85 | 65.2 | 40.32 | |||||
130 | 31.72 | 63.0 | 45.00 | |||||
112.5 | 23.23 | 46.1 | 43.81 | |||||
75 | 9.02 | 17.9 | 54.82 | |||||
1200 | 4800 | 252 | 69.12 | 137.3 | 90.85 | |||
220 | 46.08 | 91.5 | 86.36 | |||||
165 | 40.95 | 81.4 | 55.91 | |||||
130 | 38.42 | 76.3 | 62.40 | |||||
112.5 | 29.47 | 58.6 | 60.75 | |||||
75 | 11.61 | 23.0 | 76.01 | |||||
Sibirite | 1000 | 5080 | 252 | 76.56 | 42.2 | 42.2 | 50.76**** | 23.40 |
220 | 49.72 | 23.4 | 21.96 | |||||
165 | 45.68 | 21.9 | 14.40 | |||||
130 | 40.04 | 21.0 | 15.84 | |||||
112.5 | 32.92 | 15.4 | 15.48 | |||||
75 | 12.67 | 5.94 | 19.44 | |||||
1200 | 6000 | 252 | 107.91 | 52.9 | 64.06**** | 32.04 | ||
220 | 71.74 | 34.5 | 30.45 | |||||
165 | 66.74 | 32.0 | 19.80 | |||||
130 | 63.33 | 30.4 | 21.96 | |||||
112.5 | 46.08 | 21.7 | 21.44 | |||||
75 | 14.49 | 6.8 | 26.83 |
Note: * The data are given for dust dH≤ 150 μm according to the procedure (Menzhulin and Paramonov 1997); ** The data are given for dust dH ≤ 300 μm according to the procedure (Procedures of calculation of harmful emissions (effluents) for equipment of open-pit mines (on the basis of specific performances, 1990); *** The data are given for dust dH ≤ 300 μm according to the proposed procedure; ****Forecasted experimental dust weight dH ≤300 μm
Table 5. Experiments and calculations
Aiming at estimation of emitted dust with regard to size fractions for Kamennogorsk open-pit mines the weights of dust after blasting of various ES were calculated using the procedure (Menzhulin and Paramonov, 1997), it was established that the 0-300 size fraction is emitted in amount of 110.69 t. The ratios of dust size fractions in DGC (the data are comprised of dust contents after blasting of ammonite No. 6ZhV, grammonite 79/21, sibirite-1000 with the densities of 950, 870, and 1000 kg/m3, respectively), are summarized in Table 6.
Quantitative composition of dust, % | |||||
---|---|---|---|---|---|
Size fraction 0-40 | Size fraction 40-75 | Size fraction 75-150 | Size fraction 0-150 | ||
Average | 0.182 | 3.185 | 96.63 | 100 | |
For ammonite No. 6ZhV | 0.283 | 3.305 | 96.41 | 100 | |
For grammonite 79/21 | 0.145 | 2.979 | 96.87 | 100 | |
For sibirite -1000 | 0.118 | 3.268 | 96.61 | 100 | |
Quantitative composition of dust, % | |||||
Size fraction 0-150 | Size fraction 150-300 | Size fraction 0-300 | |||
Average | 54.030 | 45.968 | 100 | ||
For ammonite No. 6ZhV | 53.885 | 46.113 | 100 | ||
For grammonite 79/21 | 53.686 | 46.312 | 100 | ||
For sibirite -1000 | 54.519 | 45.479 | 100 |
Table 6. Comparison of dust fractions in dust and gas cloud upon blasting by various ES
Data analysis demonstrates that when ammonite No. 6ZhV with the density of 950 kg/m3 is used as ES the dust size fractions 0-40, 40-75, 75-150 are emitted in amount of 0.0109, 0.191, and 57.794 t/year, respectively, and the dust size fractions 0-150, 150-300 in amount of 59.81 and 50.886 t/year, respectively.
Table 7 summarizes quantitative composition of dust after blasting of ammonite No. 6ZhV with the density of 950 g/cm3 at DBore = 252 mm on the basis of procedure (Menzhulin and Paramonov 1997).
Quantitative composition of dust, % | ||||
---|---|---|---|---|
Size fraction 0-40 | Size fraction 40-75 | Size fraction 75-150 | Size fraction 0-150 | |
1 | 0.044 | 0.33 | 6.54 | 6.91 |
2 | 0.053 | 0.36 | 8.81 | 9.22 |
3 | 0.033 | 0.40 | 10.37 | 10.80 |
4 | 0.032 | 0.41 | 10.57 | 11.01 |
5 | 0.031 | 0.35 | 10.77 | 11.15 |
6 | 0.026 | 0.34 | 10.54 | 10.91 |
7 | 0.017 | 0.31 | 9.90 | 10.23 |
8 | 0.016 | 0.29 | 9.87 | 10.18 |
9 | 0.014 | 0.27 | 9.57 | 9.85 |
10 | 0.013 | 0.25 | 9.47 | 9.73 |
Table 7. Quantitative composition of dust after blasting of ammonite No. 6ZhV with the density of 950 g/cm3 at 252 DBore = mm
Therefore, this work analyzed known calculation procedures of dust and gas emissions upon drilling and blasting. It is proposed to estimate the dust and gas emissions using ammonite dust and gas equivalents. The proposed method makes it possible to estimate environmental situation at drilling and blasting sites for various ES and blasting conditions.
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